Please use this identifier to cite or link to this item: 192.168.6.56/handle/123456789/74617
Title: The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications
Authors: van Koten, Gerard
Gossage, Robert A.
Keywords: Chemistry
Issue Date: 2016
Publisher: Springer International Publishing Switzerland
Description: Pincer ligands are extensively used in many diverse areas of chemistry primarily as a means to direct and modulate the properties of a metal center to which it is bonded. The title framework emerged in the late 1970s during the pioneering organometallic chemical studies by Shaw and coworkers. In the present day, the pincer platform, with its tridentate arrangement of donor sites, is used with great success in both ligand-metal mediated catalysis, (bio)inorganic chemistry, and materials science. The first series of review papers on Pincer chemistry, published in Topics in Organometallic Chemistry (2013: Vol. 40), discussed primarily those aspects of the chemistry and applications of the prototypical monoanionic pincer-metal compounds. In this formulation, the metal center is covalently bonded via a central (sp2 or sp3 hybridized) C-metal bond in addition to two complementary interactions with neutral heteroatom donors.
URI: http://10.6.20.12:80/handle/123456789/74617
ISBN: 978-3-319-22926-3
Appears in Collections:Chemistry

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